Smoke is an aerosol consisting primarily of solid and liquid submicron particles, typically smaller than 1 micron (0.1–2 microns). Unlike larger dust particles (>3–5 microns), these fine particles have minimal inertia and easily follow gas flows, making them much harder to capture.
Smoke is a complex product of incomplete combustion, containing both particulate and gaseous matter. Carbon-based particles form the bulk of the solids and determine visible properties like color and density—for example, one cubic centimeter of woodsmoke contains about 30 million carbon particles.
In addition to particulates, emission includes gases such as carbon monoxide, carbon dioxide, water vapor, nitrogen oxides, and hydrogen cyanide. Their concentration affects optical density. Fine soot from incomplete combustion increases density, making smoke darker. Impurities in the fuel, like mineral salts or metals, can alter the exhaust’s composition and properties; for instance, chlorine can lead to hydrogen chloride formation.
This variability in composition means that effective cleaning requires specialized systems. A wood smoke scrubber must efficiently handle fine organic particles and condensable tars, while industrial coal smoke scrubbers are engineered to withstand corrosive acidic gases and often a higher load of mineral ash in addition to soot.