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Home / Blog / Landfill Gas Treatment System: Contaminant Limits, Media Sizing, Equipment Selection

Landfill Gas Treatment System: Contaminant Limits, Media Sizing, Equipment Selection

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Author:
Michael Klepik, Chief Executive Officer
Michael-Klepik
Three inputs fix the shape of a landfill gas treatment system: raw stream composition, flow and its decay over the life of the cell, and the contaminant limit on the data sheet of whatever burns or upgrades it. EPA guidance under its Landfill Methane Outreach Program treats the first two as modeled ranges, so the design case is a band.

Raw Gas Composition and Contaminant Limits

Methane runs 45–60% by volume and carbon dioxide 40–50%. Nitrogen and oxygen appear whenever wellfield vacuum pulls air through the cover, and the effect goes beyond dilution: ingress feeds aerobic zones, raises temperature in the waste mass and shifts the profile. The stream leaves the header at 90–120 °F, saturated, and composition drifts as the cell ages. Design against a twelve-month record covering seasonal swings.

Personal care products, defoamers, lubricants and cured silicone sealants put silicone-bearing material into the waste mass, where it breaks down into volatile cyclic D4 and D5 and linear L2–L5 species. Siloxanes and silicones in a landfill gas treatment system sit at different points in the chain: the silicones arrive as source material in the waste, and the siloxanes are what a sample of the stream measures. Published surveys report 1 to 136 mg/m³ of siloxanes, 5–15 mg/m³ typical at US sites. Combustion converts them to SiO₂ and microcrystalline quartz, which deposit in the combustion and exhaust stages as an abrasive white powder and drive wear and component failure. Engine builders answer by writing maximum siloxane figures into warranties.
Landfill gas scrubber system for gas cleaning and emission control.
Landfill gas scrubber system for gas cleaning and emission control.
Two conversions decide whether a published figure means anything. The first is species basis: some numbers are total siloxane mass per cubic meter, others — the California pipeline limit among them — are milligrams of silicon per cubic meter, and since D5 is about 38% silicon by mass the two differ by roughly a factor of three. The second is reference state: a concentration per m³ at site conditions and one per Nm³ are different quantities, and papers are inconsistent. The table below collects reference points with their stated basis, and is not a specification. Limits for siloxanes in a landfill gas treatment system come from the data sheet of the machine and from the interconnect tariff.
Sulfur, moisture and solids are gas-quality parameters in their own right, with acceptable values set by the end user: confirm H₂S, water dew point and particulate load per project.

Collection and Conditioning Train

Plants sold as landfill off gas collection and treatment systems begin at vertical wells and horizontal trenches, where a blower holds the waste mass under vacuum. Too little vacuum lets methane migrate through the cover; too much draws oxygen in and can trigger subsurface oxidation. Wellhead balancing against CH₄, O₂ and temperature is a monthly task, and the header pressure profile fixes the blower duty point.

A saturated stream at 110 °F holds roughly ten times the water it holds at 40 °F, so every degree of cooling in the header makes liquid. Filtration and dewatering in a landfill gas treatment system cover three jobs: sloped headers draining to sumps, a knockout vessel ahead of the blower, and a coalescing element for the aerosol the knockout misses. Condensate is aggressive, low in pH and high in chloride, calling for corrosion-rated tank equipment.
Humidity targets are set per stage. Sorbent duties pull in opposite directions: carbons impregnated for H₂S generally rely on a water film to oxidize sulfide, while capacity for organic species including D4 falls as humidity rises. Take the inlet window from the data sheet for the grade.

Take a configuration that includes a wet stage. Sequence then follows the failure mode each step prevents, and the wet stage is what makes the order counterintuitive. Solids and free liquid come out first, on an element rated for line vacuum and liquid carryover; Torch-Air's cartridge collectors cover the site's atmospheric duties. Bulk sulfur removal comes next, since consumption in any polishing charge scales with the H₂S reaching it. A wet scrubber leaves the stream saturated again, so conditioning belongs after it: cool, separate the condensate, take carryover on a coalescer, then reheat away from the dew point. Organosilicon polishing sits last, and for pipeline RNG membrane or PSA upgrading follows with its own tail-stream control device.
TORNADO-RP vertical scrubber with random packing
TORNADO-RP vertical scrubber with random packing

Equipment Types by Operating Principle

Adsorbers and dry scrubbers

Adsorbers and dry scrubbers hold a packed bed of granular sorbent and are the usual route to outlet concentrations of a few mg/m³ total siloxanes, though deep refrigeration and solvent absorption compete at some sites. Selection for siloxane compounds in a landfill gas treatment system follows the target species and site conditions.

Torch-Air's adsorber work is documented in tank-vent duty: the CO₂ breather units for water storage tanks ship with a mechanical clogging indicator and an optional analyzer fitting, and the fluosilicic acid units run lime-based sorbent. Vessel engineering, sorbent retention and change-out design carry across to fuel-gas service. Removal efficiency is a separate calculation: sorbent data gives equilibrium capacity, while the outlet concentration an operating charge holds also depends on contact time, mass transfer, geometry and loading, so confirm it by breakthrough calculation or pilot run.
Biofilter manufactured by Torch-Air
Horizontal BOREAS-P3 Wet Gas Scrubber
Sirocco Adsorber
Performance: 6000 cfm
Sirocco for Sewer
Performance: 6000 cfm
Adsorber Sirocco Flow
Performance: 0 - 4000 cfm
Adsorber Filter | Overview | Sirocco for breathing valve BIG

Wet scrubbers

Wet scrubbers take bulk H₂S and soluble VOCs upstream of the polishing charge and quench the stream at the same time. Packed towers with Pall rings, Raschig rings, Intalox saddles or Tri-Pack packing supply the contact area; the choice turns on chemical compatibility and fouling, because biological slime here blinds tight packing fast. Caustic dosing under pH control cuts sulfur loading downstream, and the saving shows in sorbent spend.
TORNADO SP Packed Bed Scrubber
Performance:
600 — 30 000 cfm
TORNADO FB Venturi Packed Bed Scrubber
Performance:
600 — 30 000 cfm
TORNADO T-RP Dual-Stage
Performance:
100 — 30 000 cfm
TYPHOON Tray Tower Scrubber
Performance:
100 — 175 000 cfm
H2S Scrubber: Design, Operational Principles, Packed Bed Systems, Tank Solutions, and Types of Media

Adsorber Sizing

Fix the reference state first: 1,200 Nm³/h at 0 °C and 101.325 kPa, inlet and outlet quoted on the same basis: 20 mg/Nm³ in, 5 mg/Nm³ as the engine target. The siloxane removal in a landfill gas treatment system duty is then 15 mg/Nm³ × 1,200 Nm³/h = 18 g/h, or 157.7 kg a year at 8,760 h. Assume 8% w/w working capacity as a figure for the worked example, and annual consumption is 1,971 kg, call it 2.0 t/y.

EBCT needs the actual volumetric flow inside the vessel. At 25 °C and 5 kPa gauge, 1,200 Nm³/h becomes 1,248 m³/h, or 0.347 m³/s. At 30 s EBCT the charge is 10.4 m³; at 3.0 m depth the cross-section is 3.47 m², a vessel 2.10 m in diameter, superficial velocity 0.10 m/s. At 450 kg/m³ bulk density the charge weighs about 4,680 kg.
TORCH-AIR adsorbers — engineered for efficient air purification.
TORCH-AIR adsorbers — engineered for efficient air purification.
At the assumed capacity that charge holds 374 kg, which against an 18 g/h duty is 20,800 h, about 2.4 years as an upper bound. Total VOC at a comparable site commonly runs near 300 mg/m³, those molecules compete for the same pore volume, and sulfur breaking through the wet stage consumes more. A charge sized on organosilicon numbers alone is exhausted well before that date, which argues for a lead-lag pair. Clean-bed pressure drop comes from the supplier curve for the mesh size at 0.10 m/s multiplied by depth, or from the Ergun equation with measured particle size and voidage; fines migration and blinding raise it over a run, so carry that margin into the blower duty.

Reported capacities are experimental results obtained under the stated conditions.

Selection and Operation

Recovery from a closed cell falls year over year, so parallel vessels with isolation valves let capacity come offline as output falls, holding contact time in range.
Fit sample ports each side of every vessel. GC-MS handles organosilicon species, detector tubes read H₂S, and differential pressure and run hours are secondary. Trigger replacement when outlet concentration reaches a set fraction of the downstream limit. Waste composition changes with what the site accepts, so a landfill gas treatment system handling siloxanes from silicone sealer waste sets its sampling interval from measured data and operating conditions.

Condensate carryover onto a warm charge is the failure that shows up most often; wetted sorbent loses working capacity, and how much returns after drying depends on the grade. Sulfur plus water attacks carbon steel headers and blower housings. Heavily loaded sorbent can run an exotherm during change-out, so cool and purge vessels before opening a manway.
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